Let $A,B,C\in \text{Obj}\webleft (\mathsf{Rel}\webright )$.
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Adjointness. We have adjunctions witnessed by bijections
\begin{align*} \mathrm{Rel}\webleft (A\times B,C\webright ) & \cong \mathrm{Rel}\webleft (A,\mathrm{Rel}\webleft (B,C\webright )\webright ),\\ \mathrm{Rel}\webleft (A\times B,C\webright ) & \cong \mathrm{Rel}\webleft (B,\mathrm{Rel}\webleft (A,C\webright )\webright ), \end{align*}
natural in $A,B,C\in \text{Obj}\webleft (\mathsf{Rel}\webright )$.